1. Electric Charge — Basic Properties

Electric charge is an intrinsic property of matter that causes it to experience a force when placed in an electromagnetic field. There are two types of charge — positive and negative — named by Benjamin Franklin.

(i) Like and Unlike Charges

  • Like charges repel each other (positive-positive or negative-negative).
  • Unlike charges attract each other (positive-negative).
  • This is the first and most fundamental observation of electrostatics.

(ii) Conductors and Insulators

Property Conductors Insulators
Charge movement Charges move freely Charges do not move freely
Free electrons Large number of free electrons No free electrons
Examples Metals (Cu, Ag, Au), graphite, human body Glass, rubber, plastic, wood, air (dry)
Charge distribution Resides on surface only Stays where it is placed

Semiconductors (e.g., silicon, germanium) have conductivity between conductors and insulators — their behaviour changes with temperature, doping, and light.

2. Fundamental Properties of Electric Charge

(i) Additivity of Charge

The total charge of a system is the algebraic sum of all individual charges. Charges add like scalars (with sign):

Qtotal=q1+q2+q3++qn

Example: A system has charges +3μC, 5μC, +2μC.
Total charge =35+2=0μC (net charge is zero).

(ii) Conservation of Charge

The total electric charge of an isolated system remains constant — charge can neither be created nor destroyed. It can only be transferred from one body to another.

  • When a glass rod is rubbed with silk, the glass becomes positive and the silk becomes equally negative — the net charge of the system (glass + silk) remains zero.
  • In pair production: γe+e+ — a photon creates an electron and a positron, conserving charge (0 → −e + e = 0).
  • In pair annihilation: e+e+2γ — charges cancel, producing uncharged photons.
  • Conservation of charge holds in all physical processes — nuclear, chemical, and mechanical.

(iii) Quantisation of Charge

Electric charge exists only in discrete multiples of the elementary charge e:

q=ne     where n=0,±1,±2,±3,

The elementary charge: e=1.6×1019 C (charge of one proton or magnitude of charge of one electron).

  • Charge of electron: e=1.6×1019 C
  • Charge of proton: +e=+1.6×1019 C
  • Charge of neutron: 0
  • Fractional charges (e/3, 2e/3) exist on quarks but quarks are never found in isolation — only integer multiples of e are observed in free particles.

At macroscopic scales, quantisation is not noticeable because the number of charges is enormous. For example, 1μC=106 C involves 1061.6×10196.25×1012 elementary charges.

Summary Table — Three Fundamental Properties

Property Statement Formula
Additivity Total charge = algebraic sum of all charges Q=qi
Conservation Total charge of isolated system is constant Qinitial=Qfinal
Quantisation Charge exists only in integral multiples of e q=ne, e=1.6×1019 C

3. Methods of Charging

(i) Charging by Friction (Triboelectric Effect)

When two objects are rubbed together, electrons transfer from one to the other. The object that loses electrons becomes positively charged; the one that gains electrons becomes negatively charged.

  • Glass rod rubbed with silk → glass becomes +ve, silk becomes ve.
  • Ebonite (hard rubber) rubbed with fur → ebonite becomes ve, fur becomes +ve.
  • Total charge is conserved — only transferred, never created.

(ii) Charging by Conduction (Contact)

When a charged conductor touches an uncharged conductor, charge flows until both reach the same potential. Both conductors acquire the same sign of charge as the original charged body.

  • If two identical conducting spheres (one charged Q, one uncharged) touch, each gets Q/2.
  • More generally, if charges Q1 and Q2 are on identical spheres that touch: each gets Q1+Q22.

(iii) Charging by Induction

A charged body brought near (but not touching) a conductor causes redistribution of charges in the conductor — the near end becomes oppositely charged and the far end becomes similarly charged. If the far end is earthed and the inducing charge removed, the conductor retains the opposite charge.

  • The induced charge is always opposite in sign to the inducing charge.
  • The original charged body loses no charge — it can charge multiple bodies by induction.
  • The net charge induced on the conductor = 0 before earthing; after earthing, the net charge equals the induced near-end charge.
Method Contact Required? Sign of Charge on Body Original Body Loses Charge?
Friction Yes (rubbing) Either (depends on material) Yes — transfers charge
Conduction Yes (touching) Same as original Yes — shares charge
Induction No Opposite to inducing charge No

4. Coulomb's Law

Coulomb's Law gives the electrostatic force between two point charges at rest. Established by Charles-Augustin de Coulomb (1785) through torsion balance experiments:

"The force between two point charges is directly proportional to the product of their magnitudes and inversely proportional to the square of the distance between them. The force acts along the line joining the two charges."

Mathematical Form

F=k|q1||q2|r2     where     k=14πε0=9×109 N·m²·C⁻²

Here ε0=8.854×1012 C²·N⁻¹·m⁻² is the permittivity of free space.

Vector Form of Coulomb's Law

The force on charge q2 due to charge q1 is:

F12=kq1q2r2r^12

where r^12 is the unit vector pointing from q1 to q2. The sign of q1q2 automatically gives the correct direction:

  • q1q2>0 (like charges): force is along +r^12repulsive.
  • q1q2<0 (unlike charges): force is along r^12attractive.
  • Newton's Third Law holds: F12=F21 — the forces are equal and opposite.

In a Medium

When charges are in a medium with relative permittivity (dielectric constant) εr (also written K):

Fmedium=14πε0εrq1q2r2=Fvacuumεr

Since εr1 for all media, the force in a medium is always less than or equal to the force in vacuum. For water, εr80 — electrostatic forces are drastically reduced.

Key Characteristics of Coulomb's Force

Characteristic Details
Nature Conservative force (work done is path-independent)
Type Central force (acts along line joining charges)
Inverse square law F1/r2 — same form as gravitational force
Superposition Holds — total force = vector sum of individual forces
Validity Valid for point charges at rest; distances from ~1015 m to astronomical scales
Medium dependence Force reduced by factor εr in a medium

5. Coulomb's Law vs Gravitational Law

Feature Coulomb's Law Newton's Gravitation
Formula F=kq1q2r2 F=Gm1m2r2
Nature Attractive or repulsive Always attractive
Constant k=9×109 N·m²·C⁻² G=6.67×1011 N·m²·kg⁻²
Medium dependence Depends on medium (εr) Independent of medium
Relative strength Fe/Fg1036 for electron-proton pair — electrostatic force is vastly stronger
Shielding Can be shielded (Faraday cage) Cannot be shielded

Ratio of Electrostatic to Gravitational Force (Electron-Proton)

FeFg=ke2Gmemp =9×109×(1.6×1019)26.67×1011×9.1×1031×1.67×1027 2.3×1039

This enormous ratio explains why gravity is completely negligible in atomic and sub-atomic physics.

6. Principle of Superposition

When multiple charges are present, the total force on any one charge is the vector sum of the individual forces due to each other charge, calculated using Coulomb's Law independently. The presence of other charges does not affect the force between any two charges.

Ftotal=F12+F13+F14+ =j1F1j

Worked Example — Three Charges in a Line

Three charges q1=+4μC, q2=2μC, q3=+3μC are placed along a line. q1 is at origin, q2 at x=0.3 m, q3 at x=0.6 m. Find net force on q2.

Force on q2 due to q1:
F21=k|q1||q2|r122=9×109×4×106×2×106(0.3)2=0.8 N
Direction: q1 is +ve, q2 is ve → attractive → force on q2 is towards q1x^ direction.

Force on q2 due to q3:
F23=k|q2||q3|r232=9×109×2×106×3×106(0.3)2=0.6 N
Direction: q3 is +ve, q2 is ve → attractive → force on q2 is towards q3+x^ direction.

Net force on q2:
Fnet=F23F21=0.60.8=0.2 N
Net force = 0.2 N in x^ direction (towards q1).

Equilibrium of Charges

For a charge to be in equilibrium, the net force on it must be zero. For a charge placed between two like charges on a line, equilibrium occurs at a point where the two repulsive forces balance. Key results:

  • For charges +Q at x=0 and +Q at x=d: a test charge +q is in equilibrium at x=d/2 (midpoint). This is unstable equilibrium.
  • For charges +Q1 at origin and +Q2 at x=d: the neutral point is at distance x=dQ1Q1+Q2 from Q1.
  • A negative charge placed between two like positive charges can be in equilibrium — and for the system of all three to be in equilibrium, specific charge ratios are required.

7. Continuous Charge Distributions

When charge is spread over an object rather than concentrated at a point, we define charge densities:

Type Symbol Definition SI Unit Element of charge
Linear charge density λ Charge per unit length C/m dq=λdl
Surface charge density σ Charge per unit area C/m² dq=σdA
Volume charge density ρ Charge per unit volume C/m³ dq=ρdV

The total force on a point charge q0 due to a continuous distribution is found by integrating Coulomb's Law over the entire distribution:

F=kq0dqr2r^