1. EMF, Internal Resistance and Terminal Voltage

EMF (ε or E) is the work done per unit charge by the battery's chemical energy source to move charge through the entire circuit (including through itself). It is the open-circuit terminal voltage.

Internal resistance (r) is the resistance offered by the electrolyte and electrodes inside the cell.

Terminal Voltage

ConditionFormulaComparison to EMF
Discharging (cell driving current)V = E − IrV < E
Charging (current forced in)V = E + IrV > E
Open circuit (I = 0)V = EV = E
Short circuit (R = 0)I_sc = E/r; V = 0Maximum current; V = 0

Current in Circuit

I=ER+rVterminal=IR=EIr=ERR+r

Example: E = 12 V, r = 0.5 Ω, R = 5.5 Ω:

I = 12/(5.5+0.5) = 12/6 = 2 A; V_terminal = 12 − 2×0.5 = 11 V

2. Cells in Series

n identical cells (each EMF E, internal resistance r) connected in series:

Etotal=nErtotal=nrI=nER+nr

Best for: High external resistance R ≫ nr. In series, total EMF is multiplied — useful when you need high voltage.

Note: If one cell is reversed: E_total = (n−2)E, r_total = nr (EMF of reversed cell subtracts).

3. Cells in Parallel

n identical cells (each EMF E, internal resistance r) connected in parallel:

Etotal=Ertotal=rnI=ER+r/n

Best for: Low external resistance R ≪ r/n. In parallel, internal resistance is reduced — useful when you need high current.

Each cell supplies only I/n — parallel combination extends battery life and handles high current loads better.

4. Mixed (Series-Parallel) Combination

m rows of n cells in series each, all m rows in parallel:

Eeff=nEreff=nrmI=nER+nr/m

Maximum current when R = nr/m (external resistance = effective internal resistance).

5. Maximum Power Transfer

Power delivered to external resistance R:

P=I2R=E2R(R+r)2

Taking dP/dR = 0: Maximum power is delivered when R = r:

Pmax=E24r(when R = r)

Verification: E = 10 V, r = 2 Ω: At R = 2 Ω → I = 10/4 = 2.5 A → P = (2.5)² × 2 = 12.5 W = E²/4r = 100/8 = 12.5 W ✓